Journal
ORGANIC LETTERS
Volume 13, Issue 4, Pages 732-735Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102968g
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Funding
- Danish National Research Foundation
- Lundbeck Foundation
- Carlsberg Foundation
- Aarhus University
- Gobierno de Espana (MICINN)
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Reductive lithiation of methyl-substituted diarylmethylsilanes using lithium naphthalenide represents a practical method for the preparation of the corresponding sillyl lithium reagents. Their addition to chiral sulfinimines affords versatile precursors to silanols and silanediols. The replacement of the currently used diphenylsilane motif by a more labile diarylsilane moiety allows the selective hydrolysis of one or two aryl groups by treatment with TFA.
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