Journal
ORGANIC LETTERS
Volume 13, Issue 7, Pages 1770-1773Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200258g
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Funding
- National Science Foundation [CHE-848637]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0848637] Funding Source: National Science Foundation
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Tetrathiafulvalene (TTF) is trapped inside a dimeric capsule formed by two octaacid, deep-cavity cavitands in aqueous solution. While the first one-electron oxidation of TTF is strongly hindered by encapsulation, the capsular assembly is eventually destabilized upon oxidation of the guest.
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