Journal
ORGANIC LETTERS
Volume 13, Issue 21, Pages 5874-5877Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202492x
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Funding
- National Natural Science Foundation of China [20972101, 21021001]
- National Basic Research Program of China (973 Program) [2010CB-833300]
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A highly enantioselective aza-Diels-Alder and Friedel-Crafts reaction sequence of N-sulfonyl-1-aza-1,3-butadienes and aliphatic aldehydes tethered to an arene motif has been developed, affording the fused chiral piperidine frameworks with a versatile scaffold diversity. A similar strategy has been applied for the construction of complex chiral tetrahydroquinoxaline structures.
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