Journal
ORGANIC LETTERS
Volume 13, Issue 22, Pages 6106-6109Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202599h
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Funding
- MEC [CTQ2007-62771/BQU, CTQ2010-20387, CSD2007-00006]
- Generalitat Valenciana [GV/2007/142, PROMETEO/2009/038]
- University of Alicante
- EU [CM0905]
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The recyclable chiral 2-aminobenzimidazole-derived organocatalyst if efficiently promotes the room temperature asymmetric conjugate addition of 1,3-diketones, beta-ketoesters, and malonates to maleimide and N-substituted maleimides, affording the corresponding Michael adducts in excellent yields and enantioselectivities even at gram scale.
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