Journal
ORGANIC LETTERS
Volume 13, Issue 8, Pages 2026-2029Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200415u
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- JSPS [20245021]
- Grants-in-Aid for Scientific Research [20245021] Funding Source: KAKEN
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The highly syn-diastereo- and enantioselective direct vinylogous Michael addition of a-thio substituted furanones with conjugate nitroalkenes was demonstrated using an axially chiral guanidine base catalyst. The method provides facile access to enantioenriched alpha,gamma-functionalized butenolides that can be further manipulated, thereby rendering them useful synthetic intermediates.
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