Journal
ORGANIC LETTERS
Volume 13, Issue 2, Pages 208-211Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102598p
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- NSERC
- Merck Frosst Canada
- University of Toronto
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An efficient rhodium(I)-catalyzed addition of arylboronic acids to (benzyl-/arylsulfonyl)acetonitrile is described. Novel beta-sulfonylvinylamine products are formed in a stereoselective fashion (Z-alkene). Upon hydrolysis, useful beta-keto sulfones are obtained with a broad scope of aryl and sulfonyl substituents.
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