Journal
ORGANIC LETTERS
Volume 13, Issue 8, Pages 2090-2093Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200499t
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- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
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An effective total synthesis of (-)-9-deoxy-englerin (4), an analogue of the natural guaiane sesquiterpene englerin A (1), has been achieved. The synthesis features a transannular epoxide opening to construct the 5,7-fused ring system followed by transannular ether formation with mercury(II) trifluoroacetate.
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