Journal
ORGANIC LETTERS
Volume 13, Issue 1, Pages 94-97Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102625s
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- ICSN
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Highly enantioselective direct amination of enamides catalyzed by chiral nonracemic calcium bis(phosphate) complex 3g afforded optically active 1,2-hydrazinoimines 4. Following a subsequent in situ hydrolysis or reduction, 2-hydrazinoketones 5 or syn-1,2-disubstituted 1,2-diamines 6 were obtained in high yields and excellent enantiomeric excess.
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