Journal
ORGANIC LETTERS
Volume 13, Issue 22, Pages 6006-6009Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202051y
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Funding
- Australian Research Council [DP0877988]
- Natural Sciences and Engineering Research Council of Canada
- Australian Research Council [DP0877988] Funding Source: Australian Research Council
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Despite broad application, few silicone-based surfactants of known structure or, therefore, surfactancy have been prepared because of an absence of selective routes and instability of silicones to acid and base. Herein the synthesis of a library of explicit silicone-poly(ethylene glycol) (PEG) materials is reported. Pure silicone fragments were generated by the B(C6F5)(3)-catalyzed condensation of alkoxysilanes and vinyl-functionalized hydrosilanes. The resulting pure products were coupled to thiol-terminated PEG materials using photogenerated radicals under anaerobic conditions.
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