Journal
ORGANIC LETTERS
Volume 13, Issue 6, Pages 1474-1477Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200154s
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- Ministry of Science and Technology of Korean government [AC3-101]
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Pd-Catalyzed oxidative alkynylation of azoles with terminal alkynes was developed via simultaneous activation of both heterocyclic sp(2) C-H and alkynyl sp C-H bonds. The choice of palladium catalyst source and external base resulted in being important factors for performing the reaction with high efficiency and selectivity, and air was successfully utilized as an environmental oxidant in the present alkynylation procedure.
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