Journal
ORGANIC LETTERS
Volume 13, Issue 3, Pages 394-397Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102682r
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Funding
- National Science Foundation [CHE 1011788]
- Arkansas Biosciences Institute
- National Institutes of Health [R15569]
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The highly enantioselective synthesis of 2-aryl- and 2-vinyl-piperidines has been accomplished through a catalytic dynamic resolution (CDR) of N-Boc-2-lithiopiperidine. The method has been applied to the synthesis of both enantiomers of the tobacco alkaloid anabasine.
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