Journal
ORGANIC LETTERS
Volume 13, Issue 20, Pages 5604-5607Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202333u
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Click phosphorylation of a propargylated unprotected peptide and phosphoryl azide using chaotrope-assisted Cu(I)-catalyzed 1,3-dipolar cycloaddition enabled a high-yielding and rapid synthesis of a nucleoside diphosphate kinase (NDPK) phosphocarrier domain. The synthesis showcases a valuable synthetic platform for the synthesis of biologically relevant phosphopeptide analogues.
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