Journal
ORGANIC LETTERS
Volume 13, Issue 20, Pages 5496-5499Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202218n
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Funding
- National Science Council [NSC 97-2113-M-001-033-MY3, NSC 98-2119-M-001-008-MY2]
- Academia Sinica
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An efficient chemical synthesis of mycothiol Involving the regioselective ketopinyl desymmetrization of 2,4,5,6-tetrabenzylated D-myo-inositol as the key step Is described. Together with a highly alpha-stereoselective D-glucosaminylation, the whole procedure was accomplished in eight steps with an overall yield of 40%.
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