Journal
ORGANIC LETTERS
Volume 13, Issue 21, Pages 5762-5765Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2023328
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- ETH Zurich
- bilateral French-Swiss Germaine de Stael programme
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Evans-type chiral lithium imide enolates undergo diastereoselective alpha-trifluoromethylation with a hypervalent Iodine-CF3 reagent with up to 91% combined Isolated yield and 97:3 dr. The resulting isolated dlastereopure products can be further transformed into valuable products without racemization.
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