Journal
ORGANIC LETTERS
Volume 13, Issue 20, Pages 5684-5687Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202415j
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- Department of Pharmacology and Vanderbilt University
- NIH [S10 RR019022]
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A short, high yielding protocol has been developed for the highly diastereoselective (dr >20:1) and general synthesis of primary beta-fluoroamines by the enantioselective alpha-fluorination of aldehydes, conversion into the N-sulfinyl aldimlne, nucleophilic addition of various organometallic species, and 1 degrees amine liberation.
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