Journal
ORGANIC LETTERS
Volume 13, Issue 13, Pages 3388-3391Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol201142v
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Funding
- National Natural Science Foundation of China
- National Basic Research Program of China [2010CB833300, 2011CB808600]
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A catalytic hydrovinylation of N-acetylenamines with ethylene is reported. This new hydrovinylation reaction is catalyzed by a ruthenium hydride complex, RuHCl(CO)(PCy3)(2), providing a series of N-acetylamines with a quaternary carbon center with up to 99% yield.
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