Journal
ORGANIC LETTERS
Volume 13, Issue 10, Pages 2690-2693Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200792v
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Funding
- MICINN, Spain [CTQ2008-06754-C04-01/PPQ]
- MAEC-AECID
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Nonterpenoid bromoallenes possessing a novel skeleton that incorporates an unprecedented [5.5.1]bicyclotridecane ring system, marilzabicycloallenes A-D (1-4), were isolated from specimens of Laurencia marilzae collected on the Canary Islands. The framework of these metabolites strongly reinforces Braddock's hypothesis concerning the biosynthesis via electrophilic bromination of the obtusallene family.
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