Journal
ORGANIC LETTERS
Volume 13, Issue 22, Pages 6130-6133Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202645z
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Funding
- National Natural Science Foundation of China [21132007, 20972145, 91021004]
- National Basic Research Program of China [2011CB921402]
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The addition of aluminum chloride to the manganese acetate-mediated radical reaction of [60]fullerene with 2-arylmalonates, 2-benzylmalonates, and 2-arylcyanoacetates can switch the reaction pathway and affords a variety of structurally novel and scarce [60]fullerene-fused tetrahydronaphthalene and indane derivatives. These products are formed probably through radical addition, followed by Friedel-Crafts-type annulation.
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