Journal
ORGANIC LETTERS
Volume 13, Issue 23, Pages 6296-6299Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202798r
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- ANR
- l'Oreal
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Functionalized alkylidene-cyclobutanes have been prepared from 2-fluoropyridinyl-6-oxy precursors derived from vinyl cyclobutanols by a radical addition elimination process. A wide range of functional groups is tolerated, and the alkylidene-cyclobutanes can be further elaborated Into cyclopentanones. The limitation of this approach resides in the competition with opening of the cyclobutane ring.
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