Journal
ORGANIC LETTERS
Volume 13, Issue 1, Pages 142-145Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102715p
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- La Sapienza University of Rome [AST 2008]
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Photochemical interconversion of the two diastereoisomers cis- and trans-thianthrene dioxide (1) can be considered an example of photodynamic combinatorial chemistry (PDCC) in which the interconversion among diastereomeric equilibrating species is brought about by electromagnetic irradiation. Photoequilibrium can be shifted by irradiation at different wavelengths or by addition of SnCl2 that binds cis-1 more efficiently than trans-1.
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