Journal
ORGANIC LETTERS
Volume 13, Issue 1, Pages 42-45Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102473k
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Funding
- Nanyang Technological University [RG50/08]
- Ministry of Education, Singapore [MOE 2009-T2-1-030]
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A mild, stereoselective, and quick approach to accessing alkynyl and alkenyl C-glycosides via BF3 center dot Et2O promoted coupling of organotrifluoroborates and glycosyl fluorides is reported. The application of this method was further demonstrated by the concise and efficient total synthesis of (+)-varitriol in only seven steps.
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