4.8 Article

Electrochemically Supported Deoxygenation of Epoxides into Alkenes in Aqueous Solution

Journal

ORGANIC LETTERS
Volume 14, Issue 1, Pages 22-25

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol2026944

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Funding

  1. National Natural Science Foundation of China [20972055, 21172080]
  2. Fundamental Research Funds for the Central Universities [2011ZZ0005]

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An efficient synthesis of alkenes from epoxides in a mixture of saturated aqueous NH4Br and tetrahydrofuran (8:1) has been developed in an undivided cell fitted with a pair of zinc electrodes, and it is proposed that the reaction Is mediated by Zn(0) with a hierarchically organized nanostructu re.

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