4.8 Article

Rh Catalyzed C-H Activation and Oxidative Olefination without Chelate Assistance: On the Reactivity of Bromoarenes

Journal

ORGANIC LETTERS
Volume 13, Issue 24, Pages 6346-6349

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol202557w

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Funding

  1. Alexander von Humboldt Foundation
  2. Deutsche Forschungsgemeinschaft
  3. Alfried Krupp Prize for Young University Teachers of the Alfried Krupp von Bohlen und Halbach Foundation
  4. European Research Council under the European Community [259368]
  5. European Research Council (ERC) [259368] Funding Source: European Research Council (ERC)

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A Rh catalyzed, no-chelate-assisted C-H activation/oxidative olefination reaction of bromoarenes has been discovered, in which the latter ones seem to act as a substrate, terminal oxidant, and catalyst modifier.

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