Journal
ORGANIC LETTERS
Volume 13, Issue 17, Pages 4668-4671Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol201891r
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Funding
- National Nature Science Foundation of China [21032005, 20972137]
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Polysubstituted pyrroles are regiospecifically synthesized via the copper-catalyzed three-component reaction of alpha-diazoketones, nitroalkenes, and amines under aerobic conditions. The cascade process Involves an N-H insertion of carbene, a copper-catalyzed oxidative dehydrogenation of amine, and a [3 + 2] cycloaddition of azomethine ylide.
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