Journal
ORGANIC LETTERS
Volume 13, Issue 19, Pages 5390-5393Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol202283d
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Funding
- MEXT, Japan
- Asahi Glass Foundation
- Kansai Research Foundation
- Toyota Physical and Chemical Research Institute
- Grants-in-Aid for Scientific Research [21106001, 23655035, 21106005] Funding Source: KAKEN
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The dehydrogenative cycloaddition of dieneynes, which possess a diene in the form of a styrene moiety and a dienophile in the form of an alkyne moiety, produces naphthalene derivatives when heated. It was found that a key requirement of this process is the presence of a silyl group attached to the alkyne moiety, which forces a dehydrogenation reaction to occur.
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