4.8 Article

A Tandem 1,3-H-Shift-6π-Electrocyclization-Cyclic 2-Amido-diene Intramolecular Diels-Alder Cycloaddition Approach to BCD-Ring of Atropurpuran

Journal

ORGANIC LETTERS
Volume 14, Issue 1, Pages 252-255

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol203030a

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Funding

  1. NIH [GM066055]

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An approach toward the BCD-ring of atropurpuran via a sequence of allenic 1,3-H shift, 6 pi-electron pericyclic ring closure, and intramolecular Diels-Alder cycloaddition of cyclic 2-amidodiene is described.

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