4.8 Article

A Benzo-21-Crown-7/Secondary Ammonium Salt [c2]Daisy Chain

Journal

ORGANIC LETTERS
Volume 14, Issue 1, Pages 306-309

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol203062w

Keywords

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Funding

  1. National Natural Science Foundation of China [20834004, 91027006, J0830413]
  2. Fundamental Research Funds for the Central Universities [2010QNA3008]
  3. National Basic Research Program [2009CB930104]
  4. Zhejiang Provincial Natural Science Foundation of China [R4100009]

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A [c2]daisy chain has been constructed from a heteroditopic monomer based on the benzo-21-crown-7/secondary ammonium salt recognition motif as shown by single crystal X-ray analysis. It has been further demonstrated that the complexation behavior of this heteroditopic monomer in solution can be controlled by changing the solution pH or adding/removing K+.

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