Journal
ORGANIC LETTERS
Volume 13, Issue 7, Pages 1824-1827Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol2003435
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Funding
- National Institutes of Health [1R01GM090280]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0840434, 0946687] Funding Source: National Science Foundation
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The first fluorous protecting group for phosphate is reported. This group can be used as a facile tag for purification and be removed under mild reducing conditions using zinc and ammonium formate. Synthesis of a disaccharide from leishmania using this fluorous protecting group demonstrated the group's stability to the acidic conditions necessary for glycosylation as well as its orthogonality to several other common protecting groups.
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