Journal
ORGANIC LETTERS
Volume 13, Issue 10, Pages 2552-2555Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol200629y
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Funding
- National Natural Science Foundation of China [21032007]
- Science & Technology Commission of Shanghai Municipality [09JC1404902]
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A novel and unexpected reaction of 2-alkynylbenzaldoxime with aryne in the presence of silver triflate (10 mol %) under mild conditions is discovered. This reaction proceeds through 6-endo-cyclization, [3 + 2] cycloaddition, and rearrangement, leading to 2-oxa-6-aza-bicyclo[3.2.2]nona-6,8-diene derivatives in moderate to good yields.
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