Journal
ORGANIC LETTERS
Volume 12, Issue 19, Pages 4388-4391Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1018739
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Aryltrimethylammonium triflates and tetrafluoroborates were found to be highly reactive electrophiles in the Pd-catalyzed cross coupling with aryl Grignard reagents. The coupling reactions proceed at ambient temperature with a nearly stoichiometric quantity of Grignard reagent, and diverse functionality is tolerated. Competition experiments established the reactivity of PhNMe(3)OTf relative to PhCl, PhBr, Phl, and PhOTf.
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