4.8 Article

Highly Selective Visual Detection of Cu(II) Utilizing Intramolecular Hydrogen Bond-Stabilized Merocyanine in Aqueous Buffer Solution

Journal

ORGANIC LETTERS
Volume 12, Issue 10, Pages 2202-2205

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol100381g

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Funding

  1. National Natural Science Foundation of China [50773091, 20702056]
  2. National Basic Research Program of China [2010CB934103]

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A Cu2+-specific colorimetric sensor 1, which is stabilized by an intramolecular hydrogen bonding, was designed and developed. The color of 1 changes from purple to blue on addition of 1.0 mu M Cu2+ in aqueous buffer solution, which can be detected by the naked eye. The analytical detection limit for Cu2+ by the naked eye is as low as 1.0 mu M. The stoichiometry for 1 and Cu2+ in complex is 2:1 in aqueous solution.

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