Journal
ORGANIC LETTERS
Volume 12, Issue 11, Pages 2646-2649Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1008558
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- CSIR
- DST
- FIST-II
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A new SET-driven reaction-based strategy is reported for sensing of cyanide with indicators having low LUMO levels. The cyanide-specific reaction produces an air-stable radical anion marker and by virtue of its spin, charge, signal outputs. High selectivity and sensitivity (0.2-16 mu M) were observed when compared to other reducing anions. This new indicator system exhibits regenerability and dip-stick sensing, and fabrication of an electronic sensing device for cyanide is demonstrated.
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