Journal
ORGANIC LETTERS
Volume 12, Issue 21, Pages 4748-4751Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102172v
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Funding
- National Natural Science Foundation of China [20802007]
- National Basic Research Program of China (973Program) [200903825300]
- Outstanding Young Scientist Foundation of NSFC [20625414]
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A highly selective synthesis of a variety of functionalized allylic 2-alkynoates was realized via the carboxylative coupling of terminal alkynes, allylic chlorides, and CO2 catalyzed by the N-heterocyclic carbene copper(I) complex (IPr)CuCl. The catalyst can be easily recovered without any loss in activity and product selectivity.
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