Journal
ORGANIC LETTERS
Volume 12, Issue 21, Pages 5060-5063Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1023135
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Funding
- The National Natural Science Foundation of China
- Shanghai Municipal Scientific Committee
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A copper-mediated oxidative cross-coupling of aryl- and alkenylboronic acids with (trifluoromethyl)trimethylsilane (Me3SiCF3) under mild conditions has been developed. This method allows a wide range of functional group tolerant trifluoromethylated arenes and alkenes to be easily prepared. This oxidative trifluoromethylation has the potential to introduce trifluoromethyl groups into advanced, highly functionalized organic molecules.
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