Journal
ORGANIC LETTERS
Volume 12, Issue 3, Pages 604-607Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9028226
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Funding
- Hong Kong Research Grants Council [PolyU 5019/06P, SEG_PolyU01]
- Areas of Excellence Scheme [AoE/P-10-01]
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A directing group-free approach for C2-selective carbenoid functionalization of NH-indoles is presented. Using [RuCl2(p-cymene)](2) as catalyst and alpha-aryldiazoesters as carbenoid source, 2-alkylated indoles were obtained in up to 96% isolated yield. Similarly, a regioselective carbenoid functionalization of NH-pyrroles was also achieved.
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