4.8 Article

Nickel-Catalyzed Ring-Opening Three-Component Coupling of Methylenecyclopropane with Aldehydes and Silanes

Journal

ORGANIC LETTERS
Volume 12, Issue 20, Pages 4536-4539

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol101838q

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Funding

  1. Sumitomo Fundation

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A nickel-catalyzed three-component coupling between methylenecyclopropane, aldehydes, and silanes afforded silylated allylic alcohols that possess an alkyl substituent at the 2-position via cleavage of the proximal C-C bond of methylenecyclopropane

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