Journal
ORGANIC LETTERS
Volume 12, Issue 17, Pages 3768-3771Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol101611v
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Funding
- National Natural Science Foundation of China [20972076, 20772061]
- Natural Science Foundation of Tianjin [10JCYBJC04000]
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A novel phosphine-catalyzed domino reaction of salicyl N-thiophosphinyl imines and allylic carbonates was developed. The allylic carbonate, in this reaction, serves as a new kind of 1,1-dipolar synthon. This method offered a powerful approach to the construction of a highly substituted trans-2,3-dihydrobenzofuran skeleton with high diastereoselectivity.
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