4.8 Article

Synthesis and Fluorescence Properties of a Pyridomethene-BF2 Complex

Journal

ORGANIC LETTERS
Volume 12, Issue 18, Pages 4010-4013

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol101612z

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A fluorescent dye, the pyridomethene-BF2 complex, has been synthesized. Although pyridomethenes did not exhibit fluorescence, pyridomethene-BF2 complexes exhibited fluorescence both in solution and in the solid state. The trifluoromethyl-substituted BF2 complex formed a J-aggregate and showed the highest fluorescence quantum yield in the solid state among all pyridomethene-BF2 complexes.

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