Journal
ORGANIC LETTERS
Volume 12, Issue 21, Pages 5024-5027Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102191p
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Funding
- National Basic Research Program of China [973-2010CB833302]
- National Natural Science Foundation of China [20872162, 20672127, 20821002, 20732008, 20702059]
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A P(p-FC6H4)(3)-catalyzed tandem reaction between ethyl 2,3-butadienoate and nitroalkenes has been developed, which involves a [3 + 2] cycloaddition and a subsequent umpolung addition. The asymmetric version of this tandem reaction has also been investigated by using chiral phosphanes.
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