Journal
ORGANIC LETTERS
Volume 12, Issue 9, Pages 1948-1951Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1003675
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It was found that beta-ketoesters were directly transformed to the corresponding alpha-hydroxymalonic esters, tartronic esters, with molecular oxygen catalyzed by calcium iodide under visible light irradiation from fluorescent lamp. This reaction includes tandem oxidation/rearrangement and has received much attention from the viewpoint of reduction of energy consumption, labor, and solvents.
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