4.8 Article

Rhenium-Catalyzed Diastereoselective Synthesis of Aminoindanes via the Insertion of Allenes into a C-H Bond

Journal

ORGANIC LETTERS
Volume 12, Issue 19, Pages 4274-4276

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ol101627x

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Funding

  1. Ministry of Education, Culture, Sports, Science, and Technology of Japan
  2. Grants-in-Aid for Scientific Research [22245017] Funding Source: KAKEN

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Aminoindane derivatives were synthesized diastereoselectively by the treatment of aromatic imines with allenes in the presence of a catalytic amount of a rhenium complex, [HRe(CO)(4)](n). The allenes inserted into the aromatic C-H bonds.

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