Journal
ORGANIC LETTERS
Volume 12, Issue 9, Pages 2116-2119Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol1006136
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- NSERC
- University of Ottawa
- AstraZeneca
- Amgen
- Eli Lilly
- OGS
- FQRNT
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New biphasic conditions for the palladium-catalyzed direct arylation of electron-poor fluorinated arenes have been developed. Taking advantage of biphasic chemistry, the use of an immiscible mixture of water and an organic solvent allows complete solubilization of all components of the system, enabling the reaction to proceed at room temperature in yields up to 99%.
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