Journal
ORGANIC LETTERS
Volume 12, Issue 1, Pages 92-94Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol9023248
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- NIH [R37GM055382]
- JSPS
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R37GM055382, R01GM055382] Funding Source: NIH RePORTER
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The iridium-catalyzed allylation of sodium sulfinate to form branched allylic sulfones is reported. The reactions between various sodium sulfinates and achiral allylic carbonates occur in good yields, with high selectivity for the branched isomer, and high enantioselectivities (up to 98% ee).
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