Journal
ORGANIC LETTERS
Volume 12, Issue 13, Pages 3006-3009Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol101012n
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Funding
- MICINN [CTQ2007-67411/BQU, CTQ2007-60745/BQU, CSD2006-0003]
- AGAUR [2009 SGR 47]
- JCyL [GR169]
- ICIQ Foundation
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The Sonogashira coupling reaction is not catalyzed by Aul/dppe in the absence of Pd complexes. However, addition of 0.1 mol % of Pd(0) led to efficient cross-coupling reactions. The most plausible catalytic cycles for the Au-catalyzed cross-coupling reactions have been examined and are unlikely in the absence of Pd contamination.
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