Journal
ORGANIC LETTERS
Volume 12, Issue 4, Pages 780-783Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902848k
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- California Institute of Technology
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Preparation of the polycyclic core of the cytotoxic natural product salvileucalin B is described. The key feature of this synthetic strategy is a copper-catalyzed intramolecular arene cyclopropanation to provide the central norcaradiene. These studies lay the foundation for continued investigations toward an enantioselective total synthesis of 1.
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