Journal
ORGANIC LETTERS
Volume 12, Issue 12, Pages 2710-2713Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol100776x
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- Fonds der Chemischen Industrie
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By utilizing click chemistry and methylation, the triazolium motif was employed to design tridentate ligands that bind by electron acception instead of electron donation. As electronically inverted ligands they are able to complex sulfate ions by hydrogen bonding and electrostatic interactions. The formation of mono- or bis-tridentate complexes could be achieved by controlling the degree of methylation with the appropriate reagents and was proven by NMR spectroscopy and computational methods.
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