Journal
ORGANIC LETTERS
Volume 12, Issue 3, Pages 484-487Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902675k
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Funding
- ScotChem
- EPSRC [EP/G006695/1]
- EPSRC National Mass Spectrometry Service Centre
- EPSRC [EP/G006695/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G006695/1] Funding Source: researchfish
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A highly regloselective method towards tertiary allylic ethers via gold(I)-catalyzed intermolecular hydroalkoxylation of allenes is disclosed. Preventing subsequent Isomerization of the tertiary allylic ether products to primary allylic ethers appears to be the key to achieving high regioselectivities.
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