Journal
ORGANIC LETTERS
Volume 12, Issue 3, Pages 436-439Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol902566p
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Funding
- MEXT [2006-2011]
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An approach to the synthesis of the tetrahydropyrrololminoquinone alkaloids has been developed and applied to the preparation of N-1-beta-D-ribofuranosyltetrahydropyrroloiminoquinones. The strategy utilizes oxidative cyclization of aryl-methoxyamides by hypervalent iodine to construct the quinoline framework shared by members of this alkaloid family. The hypervalent iodine oxidant is generated in situ by anodic oxidation of iodobenzene.
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