Journal
ORGANIC LETTERS
Volume 12, Issue 10, Pages 2438-2440Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol100841y
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Funding
- JSPS [21350020, 21750086]
- Grants-in-Aid for Scientific Research [21750086, 21350020] Funding Source: KAKEN
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A Cu-catalyzed allyl-aryl coupling reaction between (2)-acyclic or cyclic allylic phosphates and arylboronates proceeds with excellent gamma-E-selectivity and 1,3-anti chirality transfer, which gives the corresponding coupling products with benzylic and allylic stereogenic centers. The wide availability and easy-to-handle nature of arylboronates, the inexpensiveness of the Cu catalyst system, and the high regio- and stereoselectivities are attractive features of this protocol.
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