Journal
ORGANIC LETTERS
Volume 12, Issue 22, Pages 5178-5181Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol102040s
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- Lycoming College
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The electrochemical and spectrophotometric characterization of the complex formed from samarium diiodide and 4 equiv of tripyrrolidinophosphoric acid triamide (TPPA) is presented. Kinetic studies indicate that the Sml(2)/TPPA complex possesses reactivity greater than the complex formed between samarium diiodide and 4 equiv of HMPA. Examples of the use of Sml(2)/TPPA in synthesis are presented.
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